INTRODUCTION TO CHEMICAL ENGINEERING THERMODYNAMICS EIGHTH EDITION J. M. Smith Late Professor of Chemical Engineering University of. Introduction to chemical engineering thermodynamics - 7th ed - Solution manual - Smith, Van Ness _ Leandro L Cavalheiro. This document is. Author: Joseph M. Smith | H. C. Van Ness. downloads Chemical, Biochemical, and Engineering Thermodynamics. Read more · Introduction to.

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Introduction to Chemical Engineering Thermodynamics - 7th ed - Smith, Van Ness & - Ebook download as PDF File .pdf) or read book online. Chemical Engineering Thermodynamics-Smith,Van Ness,Abbot - Ebook download as PDF File .pdf) or read book online. chemical engineering. Boston McGraw-Hill - McGraw-Hill chemical engineering series xviii, p.: , English, Book, Online. Introduction to chemical engineering thermodynamics.

In each case the work performed can be recovered by carrying out the reverse process and returning the body to its initial condition. This observation leads naturally to the thought that, if the work done on a body in accelerating it or in elevating it can be subsequently recovered, then the body by virtue of its velocity or elevation contains the ability or capacity to do the work.

This concept proved so useful in rigid-body mechanics that the capacity of a body for doing work was given the name energy, a word derived from the Greek and meaning "in work. In the metric engineering system, potential energy is expressed as mzglg,. Energy Conservation In any examination of physical processes, an attempt is made to find or to define quantities which remain constant regardless of the changes which occur. One such quantity, early recognized in the development of mechanics, is mass.

The great utility of the law of conservation of mass suggests that further conservation principles could be of comparable value. Thus the development of the concept of energy logically led to the principle of its conservation in mechanical processes. If a body is given energy when it is elevated, then the body conserves or retains this energy until it performs the work of which it is capable.

An elevated body, allowed his term was first proposed in by the Scottish engineer William Rankine Introduction to fall freely, gains in kinetic energy what it loses in potential energy so that its capacity for doing work remains unchanged.

Introduction to Chemical Engineering Thermodynamics - 7th ed - Smith, Van Ness & Abbot.pdf

For a freely falling body this means that: The validity of this equation has been confirmed by countless experiments. Success in application to freely falling bodies led to the generalization of the principle of energy conservation to apply to all purely mechanical processes.

Ample experimental evidence to justify this generalization was readily obtained. Other forms of mechanical energy besides lunetic and gravitational potential energy are possible.


The most obvious is potential energy of configuration. When a spring is compressed, workis done by an external force. Since the spring can later perform this work against a resisting force, the spring possesses capacity for doing work.

This is potential energy of configuration. Energy of the same form exists in a stretched rubber band or in a bar of metal deformed in the elastic region. The generality of the principle of conservation of energy in mechanics is increased if we look upon work itself as a form of energy.

This is clearly permissible, because both kinetic- and potential-energy changes are equal to the work done in producing them [Eqs. However, work is energy in transit and is never regarded as residing in a body. When work is done and does not appear simultaneously as work elsewhere, it is converted into another form of energy. The body or assemblage on which attention is focused is called the system. All else is called the surroundings. When work is done, it is done by the surroundings on the system, or vice versa, and energy is transferred from the surroundings to the system, or the reverse.

It is only during this transfer that the form of energy known as work exists. In contrast, kinetic and potential energy reside with the system. Their values, however, are measured with reference to the surroundings; i. Changes in kinetic and potential energy do not depend on these reference conditions, provided they are fixed. Introduction During the period of development of the law of conservation of mechanical energy, heat was not generally recognized as a form of energy, but was considered an indestructible fluid called caloric.

This concept was firmly entrenched, and for many years no connection was made between heat resulting from friction and the established forms of energy. The law of conservationof energy was therefore limited in application to frictionless mechanical processes. No such limitation is necessary; heat like work is now regarded as energy in transit, a concept that gained acceptance during the years following , largely on account of the classic experiments of J.

These experiments are considered in detail in Chap. A reasonable view is that something is transferred from the hot object to the cold one, and we call that something heat Q. This leads to the concept of temperature as the driving force for the transfer of energy as heat. More precisely, the rate of heat transfer from one body to another is proportional to the temperature difference between the two bodies; when there is no temperature difference, there is no net transfer of heat. In the thermodynamic sense, heat is never regarded as being stored within a body.

Like work, it exists only as energy in transit from one body to another, or between a system and its surroundings. When energy in the form of heat is added to a body, it is stored not as heat but as kinetic and potential energy of the atoms and molecules making up the body. Problems 15 In spite of the transient nature of heat, it is often viewed in relation to its effect on the body from which it is transferred.

As a matter of fact, until about , the definitions of units of heat were based on the temperature changes of a unit mass of water. Although these definitions provide a "feel" for the size of heat units, they depend on experiments made with water and are thus subject to change as measurements become more accurate.

In order to recognize a common basis for all energy units, international steam table calorie is defined in relation to joule, the SI unit of energy, equal to 1 N m. Joule is the mechanical work done when a force of one newton acts through a distance of one meter. By definition, international steam table calorie is equivalent to 4.

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By arithmetic, using the defined relations of US Customary and SI units, one international steam table Btu, written as Btu in the book, is equivalent to All other energy units are defined as multiples of the joule. The foot-poundforce, for example, is equivalent to 1. The SI unit of power is the watt, symbol W, defined as energy rate of one joule per second.

Table A. A provides an extensive list of conversion factors for energy as well as for other units. What is the value of g, and what are its units in a system in which the second, the foot, and the pound mass are defined as in Sec. Electric current is the fundamental electrical dimension in ST; its unit is the ampere A. Determine units for the following quantities, as combinations ofjkndamental SI units.

Liquidlvapor saturation pressure P Sat is often represented as a function of temperature by an equation of the form: Here, parameters a , b, and c are substance-specific constants.

Suppose it is required to represent P Sat by the equivalent equation: Show how the parameters in the two equations are related. At what absolute temperature do the Celsius and Fahrenheit temperature scales give the same numerical value?

What is the value? Introduction 1. Pressures up to bar are measured with a dead-weight gauge. The piston diameter is 4 rnm.

What is the approximate mass in kg of the weights required? Pressures up to atm are measured with a dead-weight gauge. The piston diameter is 0. What is the approximate mass in lb, of the weights required?

The reading on a mercury manometer at The local acceleration of gravity is 9. Atmospheric pressure is What is the absolute pressure in kPa being measured? The density of mercury at Liquids that boil at relatively low temperatures are often stored as liquids under their vapor pressures, which at ambient temperature can be quite large. Suggest two reasons why. The first accurate measurements of the properties of high-pressure gases were made by E. Amagat in France between and Before developing the dead-weight gauge, he worked in a mine shaft, and used a mercury manometer for measurements of pressure to more than bar.

Estimate the height of manometer required. An instrument to measure the acceleration of gravity on Mars is constructed of a spring from which is suspended a mass of 0. At a place on earth where the local acceleration of gravity is 9.

When the instrument package is landed on Mars, it radios the information that the spring is extended 0. What is the Martian acceleration of gravity? The variation of fluid pressure with height is described by the differential equation: Here, p is specific density and g is the local acceleration of gravity. Modeling the atmosphere as an isothermal column of ideal gas at A 70 W outdoor security light burns, on average, 10 hours a day.

A gas is confined in a 0. The mass of the piston and weight together is kg. Problems 17 c If the gas in the cylinder is heated, it expands, pushing the piston and weight upward. If the piston and weight are raised 0.

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What is the change in potential energy of the piston and weight? Verify that the SI unit of kinetic and potential energy is the joule. An automobile having a mass of kg is traveling at 40 m s-'. What is its kinetic energy in kJ? How much work must be done to bring it to a stop? The turbines in a hydroelectric plant are fed by water falling from a m height.

Introduction to Chemical Engineering Thermodynamics

Below is a list of approximate conversion factors, useful for "back-of-the-envelope" estimates. Use Table A. A to establish the exact conversions. The idea is to keep the conversion factors simple and easy to remember. Consider the following proposal for a decimal calendar.

The fundamental unit is the decimal year Yr , equal to the number of conventional SI seconds required for the earth to complete a circuit of the sun. Other units are defined in the table below. Develop, where possible, factors for converting decimal calendar units to conventional calendar units.

Discuss pros and cons of the proposal. Crucial to this understanding were the many experiments of James P. In their essential elements Joule's experiments were simple enough, but he took elaborate precautions to insure accuracy.

In the most famous series of measurements, he placed known amounts of water, oil, and mercury in an insulated container and agitated the fluid with a rotating stirrer. The amounts of work done on the fluid by the stirrer were accurately measured, and the temperature changes of the fluid were carefully noted. He found for each fluid that a fixed amount of work was required per unit mass for every degree of temperature rise caused by the stirring, and that the original temperature of the fluid could be restored by the transfer of heat through simple contact with a cooler object.

Thus Joule was able to show conclusively that a quantitative relationship exists between work and heat and, therefore, that heat is a form of energy. What happens to this energy between its addition to and transfer from the fluid? A rational concept is that it is contained in the fluid in another form, called internal energy. The internal energy of a substance does not include energy that it may possess as a result of its macroscopic position or movement.

Rather it refers to energy of the molecules internal to the substance. Because of their ceaseless motion, all molecules possess kinetic energy of translation; except for monatomic molecules, they also possess kinetic energy of rotation and 'These experiments and their influence on the development of thermodynamics are described by H. Gord, and Terrence R. Dual-chirp Fourier domain mode-locked optoelectronic oscillator.

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